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Title | Mercaptobenzothiazole-on-Gold Biosensor Systems for Organophosphate and Carbamate Pesticide Compounds. |
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Author | Somerse, Vernon Sydwill. |
Subject | Mercaptobenzothiazole |
Subject | Polyaniline |
Subject | Acetylcholinesterase |
Subject | Self-Assembled Monolayer |
Subject | Organophosphates |
Subject | Carbamates |
Subject | Pesticides |
Subject | Organic Phase Amperometric Biosensor |
Subject | Nanomolar Detection Limit |
Subject | Voltammetry. |
Date | 2007 |
Type | Thesis and dissertation |
Format | |
Abstract | This study firstly reports the development, characterisation, and application of thick-film acetylcholinesterase (AChE) biosensors based on a gold electrode modified with a mercaptobenzothiazole (MBT) self-assembled monolayer and either poly(omethoxyaniline) (POMA) or poly(2,5-dimethoxyaniline) (PDMA) in the presence of polystyrene(4-sulphonic acid) (PSSA). The Au/MBT/POMA-PSSA/AChE and Au/MBT/PDMA-PSSA/AChE biosensors were then applied to successfully detect standard organophosphorous and carbamate pesticides in a 0.1 M phosphate buffer, 0.1 M KCl (pH 7.2) solution. Secondly, it reports the construction of the Au/MBT/PANI/AChE/PVAc thick-film biosensor for the determination of certain organophosphate and carbamate pesticide solutions in selected aqueous organic solvent solutions. |
Identifier | http://etd.uwc.ac.za/index.php?module=etd&action=viewtitle&id=gen8Srv25Nme4_1006_1264535891 |